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NRir(?W4l秐瞞-N剉5u粂筫 z_fN橯cknx剉/f( ) A.H2CO3  2H++CO  B.Ba(OH)2  Ba2++2OH C.NaHCO3=Na++H++CO  D.AlCl3=Al3++3Cl15.鴙 T)n N sQ嶯衯x憣T嫅x懚n瞞剉魦誰cknx剉/f( ) A.pH鴙I{剉$N秐瞞c(CH3COO-)=c(Cl-)B.pH=3衯x憣T嫅x懚n瞞 I{SO飝鱩TT秐瞞剉pH>3C.SmGW:N0.1molL"1衯x憣T嫅x懚n瞞 黐5u齹汻鴙 TD.鴙 TSm剉$N秐瞞 R+RNNaOH鶹SO蚐擽THT-N'`剉秐瞞-N(齙eu秐瞞SO飝豐S)c(CH3COO-)=c(Cl-)16."l'lS軘鰛SO(W5u髄鰁 僛剉鰛抾T4杹g鹹≧ (W購蛓鰛SO-NR+R鬾燫 NRir( NO裇u軶Z€剉/f( ) `$呏|秐瞞0a$kxx慉暥n瞞0b$Exx戹€SO0c$"l'lS翑鰛SOA.`$a$ B.`$c$ C.a$b$ D.b$c$孨0鼅T槝qQ4槝 17.皊 g NRAS蛓ir(`$瞞`/lS"la$\蟼Sb b$鶹SO瘇眡 c$孨'lS硏d$a勚| e$"l'lS緮 f$"l'lS翑鰛SO g$(l4l h$zzl i$kxx懥敹n瞞 1  N饛AS蛓ir(?N ^\嶯5u銐(崉v g________ ^\嶯^?u銐(崉v g________ 2  g$N蛓ir(?W4l秐瞞-N颯裇u蚐擽 粂P[筫 z_:NH++OHc?H2O 鍕蚐擽剉Sf[筫 z_:N________ 3 d柣Sb$-N\蠎a$剉蚫\O/f________ Sf[筫 z_:N________ 4 h芉秗礠 N ________Lc$-N+T g0.4mol 'l烻P[ 5 皊 g100mLi$秐瞞-N+TFe3+5.6g R秐瞞-NSO42cvir(崉v蠎Sm/f________ 6 鍌(Wf$-Nba燫eQe$ u剉皊a?f________ 7 \`$燫eQ0Rg$-N g$剉黐5u齹汻豐S:N________kX 瀀:_ 0 螿1_ b 鶺,gN豐  18.孾b NRkXzz 1 皊 g NRir(`$孨'lS硏CO2 a$硏x憼Na2CO3 b$邩衯4l c$爺Na  鲖(u廭鱏孾b NRkXzz N饛踁蛓ir(?NUS(?f________'lSir/f________衯{|/f________^\嶯5u銐(崉v/f________^\嶯^?u銐(崉v/f________ 2 h芉秗礠 N SO飝:N11.2L 剉CO2________mol ________*NCO2  3 纇寶NaCl7h罷-N/f&T+TKCl擽 ?u剉筫誰/f________ 19.Y嶯 NR秗`剉ir(?N`$/lS爺鶹SO a$r^癚 b$HCllSOc$軘 d$kxx憽旡VSO e$呏| f$YN噾 g$攓崌剉]xx懢敔 h$NaCl秐瞞 1 齹黐5u剉/fkX鱏  N T ________ 2 ^\嶯5u銐(崉v/f________ 3 ^\嶯^?u銐(崉v/f________ 20.桘 Nb楉w噀0IQ剉ce\NN緩\He擽IQ惽廔Qf['`(NGWS剉薔(嶖e鶴皊OP粂烻eg O璬筫T  €縧T O璬剉皊a 饄:NIQ剉ce\0(W梖虘 \N_g蟸Z€茤T剉IQ縹昩\0R鰛SO鹼邁 N (WNeQ\IQ俉魐剉筫T N 颯聣遊0RNagf甆剉IQ飴 購1\/fN緩\He擽0uN緩\He擽剉瀃(?fIQ剉ce\0h? 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NvQ4l秐瞞-NX[(W陙1u鹹≧剉粂P[ 郪dkMgSO4秐瞞齹黐5u 郪dkMgSO4:N5u銐( C&{T槝aD.CO2:NSTir vQ4l秐瞞齹黐5u /f1u嶯CO2NH2O蚐擽b_b剉H2CO3  5u粂u陙1u鹹≧剉粂P[ w嶞[5u\O(u 郪dkCO2N^\嶯5u銐( DN&{T槝aEeT{Hh:NC 0R恎05u銐(?fc(W4l秐瞞b攓崌秗` N齹黐5u剉STirncdk觺T 恲楡b賬ir(嵺廘R恎010.0T{Hh0 B 0銐恎00銐T{0銐A邩衯4l/f/lS爺剉4l秐瞞 [rvY0F孎m龕/f鰛SO EeA曪 B榵R?f榵US(崉v4l秐瞞 錶4l/fJm瞞 @埐m:N鰛SO EeBcknxC}v謡4l/f呏|4l秐瞞 邩衯4l/f/lS爺4l秐瞞 6凍S4l/f秐瞞 EeC曪DCaOH 2琡Jm瞞:NJm瞞 刼n體pp4l/f秐瞞 體ppFm:NJm瞞 EeD曪Ee 怋0R恎0秐瞞0鰛SO0Jm瞞/f N蛓N T剉Rce鹼 Rce鹼 cgqRce(崉v魐刜'Y\颯R:N秐瞞0鰛SO0Jm瞞 A[rvY:N藛}v(峛_b剉Rce鹼:N鰛SOB榵R?f榵US(崉v4l秐瞞 錶4l/fJm瞞 @埐m:N鰛SOC邩衯4l:N秐瞞N/fJm瞞D"l'lS檾琡Jm瞞:NJm瞞 體ppFm:NJm瞞11.0T{Hh0 B 0銐恎00銐T{0鰛抾(W5u:W剉\O(u N ZP歔T袕≧ 購蛓皊a岎y:N5u髄 颯(uegY?ud\  EeT{Hh:NB00R恎0鰛抾(W5u:W剉\O(u N ZP歔T袕≧ 購蛓皊a岎y:N5u髄012.0T{Hh0 B 0銐恎00銐T{0銐鰛SO抾P[剉甠抾魐刜(W1c?00nmKN魰 Rce(嵁_抾魐刜\嶯1c?00nm剉/f秐瞞 'Y嶯1c?00nm剉/fJm瞞NaOH秐瞞0C2H5OH秐瞞0kxx戃敹n瞞^\嶯秐瞞 鄀N緩\He擽"l'lS翑鰛SORce(?Y\1nm^100nm ^\嶯鰛SO  gN緩\He擽 Ee 怋0R恎0漁ncRce鹼剉R{|孴'`(R恎 鰛SORce鹼wQ gN緩\皊a 闟亯$R璭鶴Rce鹼/f鰛SOsS颯13.0T{Hh0 C 0銐恎00銐T{0AT竘4l-N愻n燫eQFeCl3q檶T秐瞞 鐍韣nq竘髞瞞SOHT塺 \Pbk燫韕 6R梍"l'lS翑鰛SO EeAN&{T槝a BT"l'lS翑鰛SO-N燫eQzkxx戵伹徬 HQ裇u"l'lS翑鰛SO剉Z€塴 kxx懬徬戹e "l'lS翑塴續秐銐 郪dk瀃寶皊a?fHQub塺倝l續 KNT塴續秐銐 EeBN&{T槝aC秐瞞0鰛SONJm瞞剉,g(岤S+R:NRce(崚|P[剉魐刜'Y\ 闟 g鰛SOwQ gN緩\皊a EeC&{T槝aDExx戹€SO剉鰛抾&^?uw N"l'lS翑鰛SO鱩T\裇uZ€塴 鱩T瞞豐QmJm EeDN&{T槝a0EeT{Hh:NC0 0R恎0鰛SO萐饄鰛秗RceSO/fN蛓GWS鱩Tir (W鰛SO-N+T g$N蛓N T秗`剉ir( N蛓Rce 鍿N蛓迯韣0Rce剉N钀R/f1u甠\剉抾P[b瞞鬾@b膥b Rce(崚|P[魐刜(W1nm 100nmKN魰剉Rce鹼鰛SO/fN蛓Rce(崚|P[魐刜薔嶯梶RceSO鹼孴秐瞞KN魰剉N{|RceSO鹼 購/fN蛓貧Rce剉Y鴙NGWSSO鹼014.0T{Hh0 D 0銐恎00銐T{0AH2CO3/f1_x NekNek5u粂 ;N亯錘,{Nek5u粂:N;N H2CO3  H++ HCO  EeAN&{T槝a BBa(OH)2/f:_眡 hQ钀5u粂 Ba(OH)2Ba2++2OH  EeBN&{T槝aCNaHCO3/f1_x憍_衯 NaHCO3=Na++ HCO  EeCN&{T槝aDAlCl3/f衯 hQ钀5u粂 AlCl3=Al3++3Cl  EeD&{T槝a0EeT{Hh:ND0 0R恎0A.1_x憚v5u粂亯Rek橯 B."l'lS檾/f:_5u銐( 5u粂筫 z_(uI{鱏 C.(W4l秐瞞-N硏x憼?u粂鶴爺粂P[孴硏x?l9h粂P[ D./lS輸颯秐'`:_5u銐( hQ钀5u粂15.0T{Hh0 A 0銐恎00銐T{0A$N秐瞞-NGWX[(W5uw儓[R`c(H+)=c(OH-)+c(CH3COO-)0c(H+)=c(OH-)+c(Cl-) pH鴙I{ R$N秐瞞-Nc(H+)0c(OH-)鴙I{ @b錘c(CH3COO-)=c(Cl-) A&{T槝a BpH鴙I{sSc(H+)鴙I{ 鱩TTc(H+)N豐 R嫅x憚v5u粂s^aN鹹≧ pHN豐 蚇:N3 BN&{T槝aC嫅x慂N1_x (W4l秐瞞-NN孾hQ5u粂 @b錘Sm}?q鴙 T FO嫅x懚n瞞-N剉粂P[Sm鬴\ 黐5u齹汻1_ CN&{T槝aD蚐擽T剉秐瞞-NGWX[(W5uw儓[R`c1(Na+)+c1(H+)=c1(OH-)+c(CH3COO-)0c2(Na+)+c2(H+)=c2(OH-)+c(Cl-) 秐瞞HT-N'` R gc1(Na+)= c(CH3COO-) c2(Na+)=c(Cl-) 1u嶯嫅x慂N1_x @b錘緩0R-N'`鰁燫eQ剉NaOH鶹SO儚\ Rc1(Na+)<c2(Na+) @b錘c(CH3COO-)<c(Cl-) DN&{T槝aEeT{Hh:NA0 0R恎0A.9hnc5uw儓[R`sS颯$R璭 B.鱩TirKNTN豐 C.黐5u齹汻孴@b&^5uw儗T粂P[Sm gsQ鹼0嫅x?f1_5u銐( D.9hnc5uw儓[R` 峇觺T-N'`sS颯$R璭16.0T{Hh0 B 0銐恎00銐T{0"l'lS軘鰛SOZP5u髄鰁 鰛抾T4杹g鹹≧ "l'lS軘鰛SO-N剉鰛抾&^ck5u `$呏|秐瞞^\嶯^?u銐(嵍n瞞 N齹O鰛SO裇u軶Z€a$kxx慉暥n瞞^\嶯5u銐(嵍n瞞 齹O鰛SO裇u軶Z€b$Exx戹€SO剉鰛抾&^?uw 颯錘O"l'lS軘鰛SO裇u軶Z€c$"l'lS翑鰛SO剉鰛抾&^ck5uw N齹O"l'lS軘鰛SO裇u軶Z€ EeB&{T槝a EeT{Hh:NB 0R恎09hnc5u髄皊a宻S颯鍂S?l'lS軘鰛抾&^ck筽 燫eQir(NO軶Z€颯錘燫eQ^?u銐(b€/f燫eQ&^ T7h5uw儎v鰛SO觺T 恲樭廘?R璭sS颯孨0鼅T槝17.0T{Hh0 1 `$a$b$e$c$d$ 2 HCl+KOH=H2O+KCl 3 燫韕2NaHCO3  Na2CO3+H2O+CO2? 4 4.48 5 1.5mol/L 6 u塺倝l續 7 瀀:_ 0銐恎00銐T{0銐1 `$瞞`/lS"l(W4l秐瞞-N齹黐5u /f5u銐(a$NaHCO3(W4l秐瞞b€攓崌秗` N齹Y黐5u /f5u銐(b$鶹SO瘇眡(W4l秐瞞b€攓崌秗` N齹Y黐5u /f5u銐(c$a勚|(W4l秐瞞孴攓崌秗` N龕N齹Y黐5u /f^?u銐(d$BaOH 2(W攓崌秗` N齹黐5u /f5u銐(e$"l'lS緮(W4l秐瞞b€攓崌秗` N齹Y黐5u /f5u銐(f$"l'lS翑鰛SO^\嶯鱩Tir 鈋N/f5u銐(峗NN/f^?u銐(g$(l4l^\嶯鱩Tir 鈋N/f5u銐(峗NN/f^?u銐(h$zzl^\嶯鱩Tir 鈋N/f5u銐(峗NN/f^?u銐(i$kxx懥敹n瞞^\嶯鱩Tir 鈋N/f5u銐(峗NN/f^?u銐(Ee^\嶯5u銐(崉v/f`$a$b$e$ ^?u銐(崉v gc$d$EeT{Hh:N`$a$b$e$c$d$2 粂P[筫 z_:NH++OHc%H2O 颯h圍y:_xN:_眡蚐擽ub颯秐'`衯孴4l剉粂P[蚐擽 俌HCl+KOH=H2O+KClEeT{Hh:NHCl+KOH=H2O+KCl3 9hnc硏x憼敔R韕NR銐 硏x?l爺燫韕R銐梍0R硏x憼04l0孨'lS硏 @b錘d柣S鶹SO瘇眡-N\蠎\蟼Sb剉蚫\O/f燫韕 筫 z_:NEeT{Hh:N燫韕2NaHCO3  Na2CO3+H2O+CO2?4 nCO2 =  nO =0.2mol VCO2 =0.2mol22.4L/mol=4.48LEeT{Hh:N4.485 Fe3+剉ir(崉v蠎:N  =0.1mol 秐瞞-N2nSO42c =3nFe3+  RSO42cvir(崉v蠎:N0.1mol  =0.15mol SO42cvir(崉v蠎Sm:N  =1.5mol/LEeT{Hh:N1.5mol/L6 鍌(W"l'lS翑鰛SO-Nba燫eQ"l'lS緮 鰛SO裇uZ€塴 u剉皊a?fu塺倝l續EeT{Hh:Nu塺倝l續7 (l4l-N剉N4lT(l/f1_5u銐( 钀R5u粂u鶴陙1u鹹≧剉粂P[Sm儚\ 燫eQ衯xT蚐擽ub/lS鯏/f:_5u銐( 孾hQ5u粂 @b錘粂P[Smn瀀'Y 黐5u齹汻n瀀:_ 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