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T術秐瞞-NHQ燫eQ衯x憍S  gf>f皊a 抍d枂N鰯粂P[r^pb 峇燫eQBaCl2秐瞞  g}vr倝l續u 鍕塴續N歔/fkxx憽 R烻秐瞞-NN歔 gSOeq \o\al(2",4) EecknxC. u塴續颯齹/fkxx憽 貜颯齹/f/lS鰯 烻秐瞞NN歔 gAg+X[(W Ee曪D. }vr倝l續颯齹/f硏x憽0硏x憴擨{ 烻秐瞞NN歔 gCa2+X[(W Ee曪鼅 N@b饛 ,g槝 怋09. 0T{Hh0C0銐恎0鍕蚐擽-N0旵Q }剉ST鱊豐S:N+2鱊?+7鱊 1Y5uP[ST鱊GS貧 0暬yP[\O貜烻BR'lCQ }剉ST鱊N豐 @b錘RCQ }梍5uP[ST鱊M朜O R2 EMBED Equation.DSMT4 \O'lSBR sSR2 EMBED Equation.DSMT4 NMn2+剉ir(崉v蠎KN詋:N56"2 9hncTCQ }剉烻P[圼R`橯鶴v^M憇^鍕筫 z_:N8H2O+5R2 EMBED Equation.DSMT4 +2Mn2+=2MnOeq \o\al(",4)+10R EMBED Equation.DSMT4 +16H+ 9hnc5uw儓[R`梍-5n+222+(210)+116 n20Ee 怌010. 0T{Hh0B0銐恎0NaClO3+6HClNaCl+3Cl2?+3H2O-N /lx憼?NClCQ }剉ST鱊1u+5鱊M朜O:N0 衯x?NClCQ }剉ST鱊1u-1鱊GS貧:N0 'lSBR:NNaClO3 1udk梍0R貜烻ir:N1mol 貜烻BR:NHCl HCl珗'lS 9hnc5uP[梍1Y圼R`颯鍂'lSir:N5mol R'lSir孴貜烻ir剉(嵪懺k:N56"10T{Hh 怋011. 0T{Hh0B0銐恎0 "&*68:>BDFHT磉瘟尺姌蝯gzWzE7h猭5ha)M5丂 PJh"h猭5h獴5丂 CJ,PJaJ,hhgj5丂 CJ,PJaJ,ho(%h猭5h獴5丂 CJ,PJaJ,ho(h獴5丂 CJ,PJaJ,ho(hja5丆J$PJaJ$ho(ho`5丆J$PJaJ$hhgj5丆J$PJaJ$ho(h,iX5丆J$PJaJ$ho(h%i5丆J$PJaJ$h!h0oLh獴5丆J$PJaJ$ho(h%i5丆J$PJaJ$ho(#jh0oLh獴5乁mHnHu8HT@ * , l xgg劋dh9DWD`劋gdgjm$$劍1$WD`劍a$gdgjm$$劍1$WD`劍a$gd%im$$  y劑1$H$WD`劑a$gd,iX$勌1$WD`勌a$gdo$dh1$H$WD`a$gd$dh1$H$WD`a$gd獴 $dhG$a$gd獴 TVXB D       " ( * , j l € 蹶蹶蹶踽坌坌坌坩坌瓶锌雄懈郾晲晢晢晈sshgjjhgjUhgjH*PJh )hgjH*\ hgj\h )hgj\h$hgjKH\h$hgj5並Hh%i5並Hh,iXKHo( h舕~h,iXh,iXOJQJ^Jh,iXOJQJ^Jo( h,iXKHhYh,iXKHh,iXh僠@ KHh,iXhw@ KH+  0 Z  D t @Bt8>DJ^$dh$9DIfWD`a$gd t<m$劋dhWD`劋gdgjm$劋dh9DWD`劋gdgjm$   2468:<>TVZ\`bhj|~€铈徭徭铞邛铈墟哨骖瞿邛铈芥墟墟铞内鳅鲱骖鲒鳅鲱驷驷嫘嫘骖瞿邛铈铞邛 hgj\乷( hgjH* hgjH*\h )hgjH*\hgjH*PJ hgj\h )hgj\jhgjUhgj hgjH*JJL\^`b^`bvx $&*,468PRV\bhnrxz "&铈苕苕苕张孳孳孳嬲沛苕苕张孳孳孳孳嬲沛真沛沛沛沛芾娑娑梨苕梨舵独孳娑梨h )hgjH*\ hgj\h? hgjOJQJ\乛Jo( h )hgjh )hgjH*\h )hgj\jhgjUhgj hgjH*H^`dnzY@@@@$dh$9DIfWD`a$gd t<m$kd$$If杔擔謀?E6 U€€€€€ t?2K44 layt t<Y@@@@$dh$9DIfWD`a$gd t<m$kd$$If杔擔謀?E6 U€€€€€ t?2K44 layt t<4Y@@@@$dh$9DIfWD`a$gd t<m$kdz$$If杔?謀?E6 U€€€€€ t?2K44 layt t<46:BJPY@@@@$dh$9DIfWD`a$gd t<m$kd7$$If杔?謀?E6 U€€€€€ t?2K44 layt t<PR|YA000劋dh9DWD`劋gdgjm$ 9U劋dh9DWD`劋gdgjm$kd$$If杔?謀?E6 U€€€€€ t?2K44 layt t<*\~V8 hj 2X~(  劋dh9DWD`劋gdgjm$劋dh9DWD`劋gdgjm$&(:<>@BDFPRrtxz€*,.0246rtbflnprt黧铉筲篦谛谒诹诹粟汹黧铉筲篦谛邝箢珞怏髭汹邻邻粟写冥棿诹jh )hgjU\j<嘔a h )hgjUV\jh )hgjU\h )hgjH*\ hgj\h )hgjH*\h )hgj\ hgjH*hgjH*PJ hgjH*hgjjhgjU8>@BDPRdfhjlnp(:<DFrt€漶郧漶戒癍犱駱攺垟償橊s窠窠n窠窠駍駍駍駍 hgj\h? hgjOJQJ\乛Jo( hgjH*hgjH*PJ hgjH*hgjjhgjUj h )hgjU\j>嘔a h )hgjUV\h )hgjH*\jh )hgjU\j=嘔a h )hgjUV\jh )hgjU\h )hgj\ hgjH*\?  "*,.0>@BDHPRTVXdfhjlvxz| 栩栩栩栩栩栩栩栩楮蝥蜩蝥蜩楮蝥蜩栩楮蝥蜩蜩蜩蜩蜩蜩蜩蜩蜇蜩吻 hgjH*\h )hgjH*\h? hgjOJQJ\乛Jo(h )hgjH*\h )hgj\ hgj\N"$,.@BDFHJLNTVXZ^`bdhjln€  栩嘬仔芩茑梁候栩嘬仔芩茑梁候梁梁栩狉栩嘬仔芩茑h )hgj4*\h? hgjOJQJ\乛Jo( hgjH*\h )hgjH*\ hgjH*hgjH*PJ hgjH*hgjjhgjUh )hgjH*\h )hgj\ hgj\?$&NPdjtvz|~€$&pt鲲巛巛缲巛巛巛缛缲巛巛巛缇葭葭葭葭葭葭葭葭葭葭坟巛巛绶冂葭风葭冂葭坟巛冂 hgjH*\h#hgj6乗h? hgjOJQJ\乛Jo( hgj\h )hgjH*\h )hgj\ hgjH*\h )hgjH*\丠:l6>^ < t 劍dhWD`劍gdgjm$p$劋dh9DWD`劋gdgjm$HJLNPRxz@H`dx€ "&(lnxz,.PV€$&8:<鲱鲱轭鲱鲱鲱鲱轭鲱喏铋铞钸鲱轭疹轭轭瘴铞铞钫晤鲱鲱鲱鲱轭鲱轭轭轭轭鲱穷炕腔hgjjhgjUhgjH*PJ hgjH*\h )hgjH*\h#hgj6乗 hgj\h )hgj\h )hgjH*\丣<>@BPR   < > t v !"!4!6!H!J!??????4"6"H"J"L"N"P"R"V"铈坻坻坻坻坻焰替兼兼叉叉碳娌娌娌娌婕娌娌娌婕婕婕娌娌娌骖霁鳅鲱hgjH*PJh )hgjH*\h? hgjOJQJ\乛Jo( hgj\h+_6hgj5乗hgjOJQJ^Jo(h )hgj\jhgjUhgj hgjH*A ^!?("??0#^#??,$?2%?8&''*()???<,??x-??劋dh9DWD`劋gdgjm$V"X"^"`"??????????????## # ######## #"#$#j$t$%%2%4%<%>%D%F%d%f%|%????????????B&D&b&d&n&p&z&|&''' '`'b'd'€'珩遵遵遵遵婉遵遵遵遵婉遵婉婉遵锐婉遵婉婉婉锐遵婉琦裢耒裢裢裢裢穹裢耒 jh庶#hgjUmHnHu hgj\h )hgjH*\h? hgjOJQJ\乛Jo(h )hgjH*\h )hgj\ hgjH*\丠€'???????????"(&(:(<(B(D(H(J(\(^(`(b(d(f(h(l(n(r(t(v(z(|(€(????????????&)().)0)2)>)@)l)n)鲱鲱鲱鲱漕蓊漕皖皖帕嫉涟僚钔钿蓊皖漭钔钔钔铞铞铞钿蓊ｎjH嘔a h )hgjUV\jh )hgjU\ hgjH*hgjH*PJ hgjH*hgjjhgjUh? hgjOJQJ\乛Jo( hgjH*\h )hgjH*\h )hgj\h )hgjH*\?n)p)r)x)z)|)????????????????????+2+4+F+H+J+L+N+P+Z+\+????????????????????? , ,,,箧拊娃酝廾藁钒帆坊藁钒帆坊藁钒帆坊廾蕖逌藁钒帆坊溵环胺晦棉 hgj\h )hgj4*\ hgjH*hgjH*PJhgjjhgjUh )hgjH*\ hgjH*\h )hgjH*\h )hgj\jh )hgjU\jn~h )hgjU\?,,,d,f,p,r,v,x,????????????????????J-L-V-X-\-^-??????????????????????????....... .".4.6.8.黜黜黜黜黜黜黜黜黜黜鬏鬏黜黜黜黜黜饔饔魉抢腔撬饔魉抢腔撬骼魉嵌狼磺索饲独 hgjH* hgjH*hgjH*PJhgjjhgjUh )hgjH*\h? hgjOJQJ\乛Jo(h )hgjH*\h )hgj\H8.:.<.>.@.????//^/`/??????<0>0R0Z0????82:2>2@2B2L2N2d2j2~2??????????????333 3D3F3??缱缱缤缱缱缛缤缱缛缱缛缛绶诅如如如诅如稂缛缱缱hgjH*PJ hgjH*hgjmHnHu jh庶#hgjUmHnHu hgj\h )hgjH*\h? hgjOJQJ\乛Jo(h )hgj\jhgjU hgjH*hgj:?^/?.0?1?>2B2?:3?4J4?45F5?6?l7?(8*8劋dh9DWD`劋gd%im$劋dh9DWD`劋gdgjm$????????????4 4P4R4|4~4??????????????55????????????6 6??????????(8*8,8箅犭犭犭犭犭陔陔犭犭孰犭陔犭犭犭犭孰孰孰孰孰孰孰犭犭犭犭烹互*hVh(85丆JKHOJPJQJaJo(hgjhV\乷( hgj\h? hgjOJQJ\乛Jo( hgj\乷(h )hgjH*\h )hgj\hgjOJQJ\乛Jo(<*8,8d8z8?H:Z:f;x;=*=€>扊??r@凘劋dh9DWD`劋gdgjm$$劋dhWD`劋a$gdgjm$$劋dh9DWD`劋a$gdgjm$$dh1$H$WD`a$gd獴 $dhG$a$gd獴$dh1$WD`a$gd裫,8.868<8@8F8N8R8V8b8d8f8j8n8p8x8z8~8磉瘟偿槉樜zgzWzE9hPkQhPkQKHPJ\?h猭5h獴5丂 CJ,PJaJ,hhgj5丂 CJ,PJaJ,ho(%h猭5h獴5丂 CJ,PJaJ,ho(h獴5丂 CJ,PJaJ,ho(hja5丆J$PJaJ$ho(ho`5丆J$PJaJ$hhgj5丆J$PJaJ$ho(h?5丆J$PJaJ$ho(h%i5丆J$PJaJ$h!h0oLh獴5丆J$PJaJ$ho(h%i5丆J$PJaJ$ho(#jh0oLh獴5乁mHnHu~8€8?????????0929????????,:.:@:D:F:H:L:N:V:Z:b:f:凓夲啁泮; ;d;f;j;l;t;x;€;嶜碲亿彝彝彝彝彝彝颐彝彝彝疾谝谝曇曇曇曇巤谝谝$h%ih%iB*OJPJQJ\乸hhPkQKH\ h )hgj\乫Hq hPkQhPkQKHPJ\h )hgj\乷( hgj\乷(h )hgjH*\ hgj\h )hgj\?h )hgjB*OJPJQJ\乸h$h,iXh,iXB*OJPJQJ\乸h.嶜扄聋披欲整?<<<\<^<b<d<j<l<~<€<侟凕咟圏夵孅忺扅｜?????唿泓辄朦===&=*=2=<=>=V=X=\=^=`=b=€>凗鲱鲱玎铉囝鲱鲱卦相允载蓬卦嘣试仡鲱囝功擃擃夘勵夘夘 hgj\h )hgjH*\$h )hgjB*OJPJQJ\乸h$h%ih%iB*OJPJQJ\乸hhPkQhPkQKHPJ\ hgjo( hgjH* hgjH*hgjjhgjUhgjH*PJ hgjH*\h )hgj\h )hgjH*\?凗咡嶠扊欮淊政???j?l???????r@v@x@€@凘孈怈扏継繞艪菮蔃蜙褸谸贎霡頏AAA"A&A(A:AR牎Jb姠$劋dh9DWD`劋a$gdgjm$劋dh9DWD`劋gdgjm$nDpD淒濪燚癉睤碊郉釪銬鍰霥頓餌EE4E6E8E:E>E@EBEnEpErEtEvE|E~E€E奅孍箅畚箅捏氪霛栯嗠碾侂捏雚d髞霛栯\jhgjUjh )hgjU\jC嘔a h )hgjUV\ hgj\h? hgjOJQJ\乛Jo( hgjH*\h )hgjH*\jh )hgjU\jB嘔a h )hgjUV\h )hgjH*\j鲽h )hgjU\jA嘔a h )hgjUV\h )hgj\jh )hgjU\?孍濫燛‥狤癊睧轊郋釫銭鍱霦頔FFFF"F$F@FFFHFPFTF\FfFhF凢咶嶧怓鶩麱€G侴阚污颈毋郦坫坫坫蹫媥踴踤踤踤踤踓hgjOJQJ^Jo(h )hgjH*\$h )hgjB*OJPJQJ\乸h$h,iXh,iXB*OJPJQJ\乸hhPkQhPkQKH\乷( hgjH*\jh )hgjU\jD嘔a h )hgjUV\jh )hgjU\h )hgj\ hgj\jhgjU hgjH*hgjH*PJhgj&侴扜楪欸瓽\bdlpx€倲啍垟湐灁瑪當皵稊笖簲紨緮聰臄財跀钄陻鞌顢麟嘏髋明胴镑镑狑涽涽憡鱻涽狑涽涽€鱴tohthgjH*PJ hgjH*hgjjhgjUh )hgjH*\ hgjH*\h )hgjH*\ hgj\h? hgjOJQJ\乛Jo($h#hgjB*OJPJQJ\乸hU$h )hgjB*OJPJQJ\乸h$h,iXh,iXB*OJPJQJ\乸hhPkQhPkQKHPJ\h )hgj\'(W'lS貜烻蚐擽-N ir(崉v'lS'`:_1_sQ鹼:N'lSBR'lSir )R(udk膲媉颯鍂By樛S擽齹Y裇u012. 0T{Hh0B0銐恎0A. 1u`$颯鍂 FeCQ }剉ST鱊M朜O R'lS'`:NFe3+>SO2 1ua$颯鍂 CrCQ }剉ST鱊M朜O R'lS'`:NCr2Oeq \o\al(2",7)>Fe3+ R'lS'`Cr2Oeq \o\al(2",7)>Fe3+>SO2 EeAcknxB.6.72L SO2(h芉秗礠)耂燫蚐擽 n(SO2)=6.72L22.4L/mol=0.3mol 1u N饛$N*N蚐擽颯鍂 X[(W3SO2<"Cr2Oeq \o\al(2",7) Rg葉坢€0.1mol K2Cr2O7 EeB曪C. 蟢 g1mol K2Cr2O7耂燫蚐擽 l忹y5uP[:N1mol2(6"3)=6mol sSl忹y5uP[剉pe顅:N6NA EeCcknxD. 郪'lS'`:NCr2Oeq \o\al(2",7)>SO2 RK2Cr2O7齹\Na2SO3'lSbNa2SO4 EeDcknxEe 怋013. 0T{Hh0D0銐恎0A. 郪蚐擽-NClCQ }剉ST鱊1u+5M朜O:N+4鱊 KClO3(W蚐擽-N梍0R5uP[ RKClO3(W蚐擽-N/f'lSBR A曪B. 蚐擽-N g1mol KClO3耂燫蚐擽 ub1mol孨'lS硏孴1mol ClO2 R(Wh芉秗礠 N齹梍0R44.8LlSO vQ僛ag鯪NN歔:N44.8L B曪C. 郪CCQ }剉ST鱊1u+3GS貧0R+4鱊 1Y籗5uP[ RH2C2O4(W蚐擽-N\O貜烻BR C曪D. ClCQ }剉ST鱊1u+5M朜O:N+4鱊 R1mol KClO3耂燫蚐擽l忹y剉5uP[:N1mol(54)=1mol DcknxT{Hh 怐014. 0T{Hh0A0銐恎0A. 23g NO2:N0.5mol R+T gNA*N'l烻P[ Ay榗knxB.  gcfh芉秗礠 B曪C. M?R秐瞞鰁N齹魐\秐(嵍n嶯N歔SO飝剉4l-N0 €擽鍕/f秐嶯\蠎4l-N峇燫4lz蕬髞@b桽O飝 C曪D. 郪SO飝NwQ g燫孴'` 秐瞞剉SO飝NI{嶯100mL R燫4l80mLN齹M?Rb0.1000 mol?L"1 H2SO4秐瞞 EeD曪015. 0T{Hh0B0銐恎09hnc槝a N蛓lSOX0Y0Z剉鴙鵞RP[(嵪憇Q鹼:NMr(X)Mr(Y)=0.5Mr(Z) sSMr(X)Mr(Y)Mr(Z)A9hncm=nM= EMBED Equation.DSMT4 M RP[pe顅鴙I{剉 N蛓lSO (嵪g'Y剉/f鴙鵞RP[(嵪g'Y剉Z 皊烻P[pe顅鴙I{剉 N蛓lSO (嵪g'Y剉鄀誰$R璭 EeA曪B9hnc芠= EMBED Equation.DSMT4  lSOY(W鴙 T剉ag鯪 N R芠孴鴙鵞RP[(嵪bck詋  N蛓lSO芠g\剉/fX EeBcknxClSO剉ir(崉v蠎n= EMBED Equation.DSMT4  Vm孴lSO剉秗` gsQ  N蛓lSOSO飝GW:N2.24 L VmNN歔I{嶯22.4L/mol @b錘僛霳剉ir(崉v蠎NN歔GW:N0.1mol EeC曪D T)n N SO飝鴙 T剉$N筟hVR+REQ2gYlSO孴1gZlSO Mr(Y)=0.5Mr(Z) R孨€剉ir(崉v蠎KN詋/f46"1  T)n TSO飝剉lSOir(崉v蠎KN詋I{嶯婼:_KN詋 Y0ZlSO@bb譙剉婼:_詋:N46"1 EeD曪016. 0T{Hh0A0銐恎0/llubClO"NClOeq \o\al(",3)/f珗'lS剉菑 z ST鱊R+R1u0鱊GS貧:N+1鱊孴+5鱊 ClO"NClOeq \o\al(",3)剉ir(崉v蠎SmKN詋:N16"4 R颯緥ClO":N1mol ClOeq \o\al(",3):N4mol 珗'lS剉ClqQ:N5mol 1Y籗5uP[剉;`ir(崉v蠎:N1(1-0)+4(5-0)=21mol 'lS貜烻蚐擽-N'lSBR孴貜烻BRKN魰梍1Y5uP[pe顅鴙I{ /llubNaC1/f珗貜烻剉菑 z ST鱊1u0鱊M朜O:N-1鱊 R梍0R5uP[剉ir(崉v蠎_N擽:N21mol R珗貜烻剉Cl剉ir(崉v蠎:N21mol @b錘珗貜烻剉/lCQ }孴珗'lS剉/lCQ }剉ir(崉v蠎KN詋:N216"5 Acknx鼅 N@b饛 ,g槝 怉017. 0T{Hh0`!.1 CO2 H2O Na2CO3 2 N/f 3 COeq \o\al(2",3)+2H+=H2O+CO2? 4 HCOeq \o\al(",3)+H+=CO2?+H2O0HCOeq \o\al(",3)+OH==COeq \o\al(2",3)+H2O a!.1 c$e$ 2 `$a$b$c$g$h$ d$f$ 3 `$a$c$f$g$h$ 0銐恎0(1)`$-NCO2/f^椦慯\'lSir vQ諲龕/f褢^\'lSira$-NH2ON/fx vQ諲龕/fxb$-NNa2CO3/f衯 vQ諲龕/f眡0T{HhCO20H2O0Na2CO3(2)Sf[蚐擽:NNa2CO3+CO2+H2O=2NaHCO3 蚐擽-NCQ } g鱊`豐S N/f'lS貜烻蚐擽0T{HhN/f(3)Na2CO3/f颯秐'`衯 kxx?f:_x 粂P[蚐擽GW齹芺 @b錘Na2CO3N硩蠎zkxx懲S擽剉粂P[筫 z_COeq \o\al(2",3)+2H+=H2O+CO2?(4)HCOeq \o\al(",3)/f1_x憚vx_x?h 齹NH+0OH蚐擽 vQ粂P[筫 z_:NHCOeq \o\al(",3)+H+=CO2?+H2O0HCOeq \o\al(",3)+OH=COeq \o\al(2",3)+H2O0T{HhHCOeq \o\al(",3)+H+=CO2?+H2O0HCOeq \o\al(",3)+OH=COeq \o\al(2",3)+H2O0a!.(1)齹黐5u剉ir(?f褢^\Pg檈0JS黐SO孴5u銐(嵍n瞞b攓崌秗`剉5u銐( 郪dk錘 Nir(?N攓崌KCl0軘齹黐5u EeT{Hhc$e$0(2)5u銐(?f(W4l秐瞞b崌S秗` N齹黐5u剉STir 錘 Nir(?N`$NaCl0a$瞞`HClvfSO0b$CaCO30c$攓崌KCl鶹SO0g$H2SO40h$KOH鶹SO^\嶯5u銐(d$呏|0f$CO2^\嶯^?u銐(T{Hh`$a$b$c$g$h$d$f$0(3)秐嶯4l齹5u粂鶴陙1u鹹≧剉粂P[ 秐瞞Mb齹0R黐5u 錘 Nir(?N`$NaClvfSO0a$瞞`HCl0c$攓崌KCl0f$CO20g$H2SO40h$KOH鶹SO秐嶯4lT龕齹黐5uT{Hh`$a$c$f$g$h$018. 0T{Hh01 +1 'lS Cl2+2OH"=Cl"+ClO"+H2O 2 2ClOeq \o\al(",3)+SO2=ClO2+SOeq \o\al(2",4) 26"5 3 Cu0H0Cl 2H2S+O2=2S?+2H2O 0銐恎0(1)NaClO-NNaCQ }/f+1鱊 OCQ }/f-2鱊  gckST鱊剉鉔pe孴颯鍂ClCQ }剉ST鱊:N+1鱊 !k/lx憼攚Q g:_'lS'`  g@g虄坢襨剉\O(u/ll孴"l'lS爺蚐擽ub/lS爺0!k/lx憼攲T4l 蚐擽剉粂P[筫 z_:NCl2+2OH"=Cl"+ClO"+H2O(2)`$KClO3NSO2(W:_x?`秐瞞-N蚐擽颯6R梍ClO2  T鰁擽ubkxx懢 蚐擽剉粂P[筫 z_:N2ClOeq \o\al(",3)+SO2=ClO2+SOeq \o\al(2",4)a$ClO2颯\焇4l-N剉Mn2+lS:NMnO2 €d柣S ,g珟貜烻:NCl" 蚐擽-NClO2:N'lSBR ClCQ }ST鱊1u+4鱊M朜O:N-1鱊 Mn2+:N貜烻BR CQ }ST鱊1u+2鱊GS貧0R+4鱊 'lSBR孴貜烻BR梍1Y5uP[pe顅鴙I{ R'lSBR孴貜烻BR剉ir(崉v蠎KN詋:N26"5(3)nc-NTCQ }ST鱊鍂 CuCQ }ST鱊龕/f+2鱊0HCQ }ST鱊龕/f+1鱊0ClCQ }ST鱊龕/f-1鱊 @b錘ST鱊N豐剉/fCu0H0ClCQ }:y蚐擽ir:NH2S孴O2 ubir:NS孴H2O Fe2+孴Cu2+w崿PS\O(u 裇u剉;`蚐擽:N2H2S+O2eq \o(=====,\s\up7(琍SBR))2S?+2H2O019. 0T{Hh01 (2b-4a)/V 2 d$ c$ 3 1.5 4 16"26"26"1 5 10Al+6NOeq \o\al(",3)+4 OH==10 AlOeq \o\al(",2)+ 3 N2?+2 H2O 6 I20KIO3  0銐恎01 Ba2+孾hQ塴續 坢€a mol H2SO4 Ba2++SOeq \o\al(2",4)=16"1 sS ga mol剉BaCl2 1\ g2amol Cl" 亯OCl"孾hQ塴續 梺塨 mol AgNO3 Ag+6"Cl"=16"1 ;`qQ gb mol剉Cl" 螿籗BaCl2 -N+T g剉2a mol Cl 1\/fKCl-N+T g剉Cl" K+粂P[孴Cl":N16"1剉sQ鹼 @b錘K+粂P[剉ir(崉v蠎Sm:N EMBED Equation.DSMT4 = EMBED Equation.DSMT4 mol/L2 `$S剉ST鱊Y嶯-N魰鱊` @b錘鈋 g'lS'`萐 g貜烻'`a$SOeq \o\al(2",3)-NS剉ST鱊Y嶯-N魰鱊` @b錘鈋 g'lS'`萐 g貜烻'`b$Fe2+剉ST鱊Y嶯-N魰鱊` @b錘鈋 g'lS'`萐 g貜烻'`c$Al3+剉ST鱊Y嶯g貧鱊` 闟 g'lS'`d$Na剉ST鱊Y嶯gNO鱊` 闟 g貜烻'`e$HCl-N"lCQ }剉ST鱊Y嶯g貧鱊` 闟 g'lS'`ClCQ }剉ST鱊Y嶯gNO鱊` 闟 g貜烻'`@b錘HCl鈋 g'lS'`萐 g貜烻'`f$Na2O2-NNaCQ }剉ST鱊Y嶯g貧鱊` 闟 g'lS'`O剉ST鱊Y嶯-N魰鱊` @b錘鈋 g'lS'`萐 g貜烻'`觺T錘 NR恎颯鍂 (WSf[蚐擽-N 鍕ir(峑P貜烻BR 闟齹珗'lS剉/fd$鍕ir(嶊SZP'lSBR 闟齹h埌s鶴'lS'`剉/fc$3 )R(u5uP[圼R` S_1mol Cr3+珗'lS:NCr2Oeq \o\al(2",7)0.5mol 鰁 @b1Y籗剉5uP[pe:N3mol 購汵5uP[珗PbO2梍0R  €1mol PbO2珗貜烻闟梍0R2mol5uP[ 郪dk梺塒bO2剉ir(崉v蠎:N1.5mol4 菑'lS"l-N'lCQ }剉ST鱊/f-1鱊 貧0晉懢0/lx懢?N'lCQ }剉ST鱊GW:N-2鱊菑'lS爺-N'lCQ }剉ST鱊:N-1鱊 @b錘S_6R梍 T)n0 T婼 N鴙 TSO飝剉'll鰁 踁*N蚐擽-Nl忹y剉5uP[peKN詋:N16"26"26"15 Al?AlOeq \o\al(",2)-N 輸CQ }ST鱊GS貧哊3鱊 2NOeq \o\al(",3)?N2-N .lCQ }ST鱊GS貧哊5鱊 qQ豐S哊10鱊9hnc'lS貜烻蚐擽-NST鱊GSM曽`pe鴙I{膲媉颯鍂 AlkX鹼pe10 AlOeq \o\al(",2)kX鹼pe10 NOeq \o\al(",3)kX鹼pe6 N2kX鹼pe3 gT9hnc5uw儓[R`蔛烻P[圼R`M憇^vQ僛ir(崉v鹼pe wQSO俌 N10Al+6NOeq \o\al(",3)+4OH=10AlOeq \o\al(",2)+3N2?+2H2O6 `$(W'lS貜烻蚐擽-N CQ }ST鱊剉豐SN裇u蚐擽剉sQ鹼/f GS1Y'l M枟_貜 鍌魦BR ck鴙蚐 0(WKMnO4+KI+H2SO4?MnSO4+I2+KIO3+K2SO4+H2O蚐擽-N 0旵Q }ST鱊1u+7鱊M朜O:N+2鱊 0旵Q }珗貜烻 貜烻ir/fMnSO4 KMnO4/f'lSBR ICQ }剉ST鱊1uc?鱊GS貧:NI2-N剉0鱊孴KIO3-N剉+5鱊 KI\O貜烻BR 裇u'lS蚐擽 a$鍕蚐擽筫 z_-NI2孴KIO3剉蠎peR+R/f/f6孴3 R12KI^6I2 3KI^3KIO3 蚐擽-N榵CQ }1Y籗剉5uP[;`pe:N[0cc? ]12+[+5cc? ]3=30 (W'lS貜烻蚐擽-N (uUS縹ehh圍y5uP[l忹y剉筫誰/f 蜰貜烻BR-N豐S剉CQ }鶴裇cT'lSBR-N豐S剉CQ } 郪dk鍕蚐擽-N5uP[l忹y剉筫T孴pe顅颯h圍y:N020. 0T{Hh01 10 Ca2++2OH"+CO2=CaCO3?+H2O 2 Ca2+0Cu2+ NOeq \o\al(",3) 3 K+ Cl" 0.1mol0銐恎0`$TN齆秐瞞-N燫eQ硩蠎剉NaOHSm秐瞞v^燫韕 u剉lSO(Wh芉秗礠 NSO飝:N4.48L 擽ubNH3 RN歔+T gNHeq \o\al(+,4) NnNHeq \o\al(+,4) =4.48L22.4L/mol=0.2mola$T鍿N齆秐瞞-N燫eQ0.6mol/L剉BaCl2秐瞞500mL p`}Y颯錘N秐瞞-N剉粂P[孾hQ蚐擽 菑鋘梍66.3g塴續蔛鋘瞞 塴續颯齹:NBaSO4bBaCO3b孨€龕 g 俌:NBaSO4 RmBaSO4 =0.6mol/L0.5L233g/mol=69.9g 俌:NBaCO3 mBaCO3 =0.6mol/L0.5L197g/mol=59.1g R魦f2u-N+T gSOeq \o\al(2",4)0COeq \o\al(2",3) 緥R+R:Nx mol :Ny mol Rx+y=0.30233x+197y=66.3 銐梍x=0.2 y=0.1 +T gCOeq \o\al(2",3) RN歔NX[(WCa2+0Cu2+b$T N饛塴續-N燫eQ菑蠎剉衯x u剉lSO恊Q硩蠎刼n剉體pp4l-N 梍0RN歔蠎剉塴續X lSO/f孨'lS硏 X/f硏x憴c$T N饛鋘瞞-N燫eQ1mol/L AgNO3秐瞞650mL p`}Y颯孾hQ蚐擽 颯鍂鋘瞞-NnCl" =1mol/L0.65L=0.65mol  €a$燫eQnCl" =0.6mol/L20.5L=0.6mol R魦f2u-N+T gCl" NnCl" =0.65mol-0.6mol=0.05mol 俌N+TNOeq \o\al(",3) R1u5uw儓[R`颯鍂N歔+T gK+ 1unK+ +nNHeq \o\al(+,4) =2nCOeq \o\al(2",3) +2nSOeq \o\al(2",4) +nCl"  RnK+ =20.1mol+20.2mol+0.05mol-0.2mol=0.45mol 郪Rb$N齆 R2u+T g0.4mol NHeq \o\al(+,4)00.9mol K+00.4mol SOeq \o\al(2",4)00.2mol COeq \o\al(2",3)00.1molCl" 俌+T gNOeq \o\al(",3) RK+'Y嶯0.9mol01  N饛瀃寶b$-N梍0R塴續X:N硏x憴 9hnc硏烻P[圼R`颯鍂(嵪慂N0.1mol100g/mol=10g ub塴續X剉粂P[筫 z_:NCa2++2OH"+CO2CaCO3?+H2O2 1u錘 NR恎颯鍂N歔NX[(WCa2+0Cu2+ N齹nx歔/f&T+T gNOeq \o\al(",3)3 2u+T g0.4mol NH4+00.9mol K+00.4mol SOeq \o\al(2",4)00.2mol COeq \o\al(2",3)00.1mol Cl" 俌+T gNOeq \o\al(",3) RK+'Y嶯0.9mol Rir(崉v蠎g'Y剉粂P[/fK+ir(崉v蠎g\剉粂P[/fCl" vQir(崉v蠎:N0.1mol021. 0T{Hh0`!.1 &T 9e(uBa(NO3)2OO秐瞞-N_eQ癳剉Bg(嵒yP[NOeq \o\al(",3) 2 Y梟 T NB\n瞞-N鐍韣鬾燫BaCl2秐瞞 秐瞞N豐QmJm R騗d朂\ 3 d柣S鋘瞞-N秐銐剉CO2孴YYO剉衯x a!.1 `$b$e$ 2 竸裇Sm) M?n觺vf 3 41.7 c d 0銐恎0`!.(1),g瀃寶剉顅剉g葉梍0R瘇繯剉/lS爺秐瞞 郪dk蚫\Oa$-N9e:N燫]xx憽敹n瞞 O_eQ癳剉Bg(嵒yP[NOeq \o\al(",3) 梍N0R瘇剉/lS爺 郪dkN齹(uBa(NO3)2秐瞞鉔fBaCl2秐瞞鼅 N@b饛 ,g槝T{Hh/f&T 9e(uBa(NO3)2OO秐瞞-N_eQ癳剉Bg(嵒yP[NOeq \o\al(",3)0(2)蚫\Oa$ 燫eQ/lS秐瞞 顅剉/fd柣Skxx?h粂P[ 郪dk$R璭SOeq \o\al(2",4)騗d朂\筫誰/fY梟 T NB\n瞞-N鐍韣鬾燫BaCl2秐瞞 秐瞞N豐QmJm R騗d朂\鼅 N@b饛 ,g槝T{Hh/fY梟 T NB\n瞞-N鐍韣鬾燫BaCl2秐瞞 秐瞞N豐QmJm R騗d朂\0(3)鋘瞞-NiRYO剉硏x憼N菑蠎剉衯x懲S擽ub孨'lS硏0/lS爺 郪dk蚫\Oc$蹚L垊v燫韕nq竘 vQ顅剉/fd柣S鋘瞞-N秐銐剉CO2孴YYO剉衯x鼅 N@b饛 ,g槝T{Hh/fd柣S鋘瞞-N秐銐剉CO2孴YYO剉衯x0a!.(1)蹚L埱忎n蚫\O @b(u0R剉籹僼闚hV g`$o梕 b$鏿og e$籹僼襤鼅 N@b饛 ,g槝T{Hh/f`$b$e$0(2)1u秐瞞6RvfSO鰁 亯蟸菑燫韕Sm)0稱tS觺vf0菑鋘0mI{ek,g槝-NN鹼R蚫\O 漁!k:N燫韕Sm)0M?n觺vf孴菑鋘鼅 N@b饛 ,g槝T{Hh/f竸裇Sm)M?n觺vf0(3)9hnc秐瞞z蕬MRT秐(崉v蠎N豐膲媉 瀃寶 g240mL筟蠎鰐 闟齹 ?u250mL筟蠎鰐 郪dk18V(SmH2SO4)=2503 V(H2SO4)=41.7mL瀃寶鰁  NR蚫\OO bOPNO剉/fa.筟蠎鰐匭罼D g4l鄐 €*gr^錻Yt Nq_蚑秐(崉v蠎孴秐瞞剉SO飝 鵞鄀q_蚑 N b.*g稱tS髞)n魐l忹y髞筟蠎鰐-N I{秐瞞稱tS0R)nT 秐瞞剉SO飝OOP\ @bM懚n瞞SmOP'Y N c.燫4l鰁厤菑;R縹T萐P鶴  b秐(崉v蠎螿\ @bM懚n瞞SmOPNO 颯 d.歔筟鰁餘茐;R縹  b秐瞞剉SO飝OP貧 @bM懚n瞞SmOPNO 颯 鼅 N@b饛 ,g槝cknxT{Hh/f41.7 cd0}YYe瞼慛s^餝 g-NY€緗褢wS ,{ =page 2*2-1 3uqQ =sectionPages 3*2 6u  }YYe瞼慛s^餝 g-NY€緗褢wS ,{ =page2*2 4uqQ =sectionPages 3*2 6u }YYe瞼慛s^餝 g-NY€緗褢wS ,{ =page 1*2-1 1uqQ =sectionPages 3*2 6u  }YYe瞼慛s^餝 g-NY€緗褢wS ,{ =page1*2 2uqQ =sectionPages 3*2 6u }YYe瞼慛s^餝 g-NY€緗褢wST{Hh ,{ =page 4*2-1 7uqQ =sectionPages 4*2 8u  }YYe瞼慛s^餝 g-NY€緗褢wST{Hh ,{ =page4*2 8uqQ =sectionPages 4*2 8u }YYe瞼慛s^餝 g-NY€緗褢wST{Hh ,{ =page 3*2-1 5uqQ =sectionPages 4*2 8u  }YYe瞼慛s^餝 g-NY€緗褢wST{Hh ,{ =page3*2 6uqQ =sectionPages 4*2 8u dkwS闟艌N芠\韘 覻T 芉€翄鱏 €:W鱏 MO鱏 dkwS闟艌N芠\韘 覻T 芉€翄鱏 €:W鱏 MO鱏  &(*,>@BDFHJLPRTVZ\xz~€敃枙袝視鋾鏁陼鞎饡驎魰鴷鷷鼤8:>@BDfhlnprz|铋嶙虚崞犷隽忽铋嶙虚崞衢崞衢衢衢衢崞漆铞梁鳅鲱獒漆漆漆漆漆漆獒h )hgjOJQJ\乛JhgjH*PJ hgjH*h )hgjH*\ hgjH*\h )hgjH*\h )hgj\ hgj\jhgjUhgj hgjH*D獤緰罇聳鈻鋿鏂钖鷸鼥  (*.0:<@BRTVX\^`hlt畻皸虠螚柁蜣蛑彝埔烈助蜣掾掾掾掾掾掾掾唉煂y騳蜣蜣$h#hgjB*OJPJQJ\乸h$h,iXh,iXB*OJPJQJ\乸hhPkQKH\h$hPkQKH\h )hgj\乷( hgj\乷( hgjH*hgjH*PJ hgjH*hgjjhgjUh )hgjH*\h#hgj6乗h )hgj\ hgj\/螚 24:<緲罉聵臉茦葮鏄铇 "jprz~啓姍寵槞殭皺矙礄虣螜鞕顧PR垰寶畾皻矚稓笟簹細罋職詺跉黩麒黩麒麒麒麒黩黩麒鬈啥鞫黩麒鳜蝼蝼蝼蝼楓崋麒麒鬈 hgjH*\h )hgjH*\h )hgjOJQJ\乛J hgjH*\h#hgj6乗$h#hgjB*OJPJQJ\乸h$h+sh+sB*OJPJQJ\乸hhPkQhPkQKHPJ\h )hgjH*\ hgj\h )hgj\4跉軞錃铓饸 ",.>@LNXZdf€倹疀皼矝礇:<hjln跍軠 譂貪铦隄 碲亿胰胰胰胰胰胰一耀灮一規伝一襮d灰纫纫jh )hgjU\jG嘔a h )hgjUV\j h )hgjU\jF嘔a h )hgjUV\jh )hgjU\jE嘔a h )hgjUV\jh )hgjU\h )hgjH*\h )hgj\?h#hgjB*OJPJQJ\乸h$h,iXh,iXB*OJPJQJ\乸h' VXhnpx|劄挒敒湠灋盀矠礊稙笧簽鰹鵀46FHZ\nprtvx螤袪驙鵂鸂綮綮嗨胳胳膘━饱牓╈膘━饱牓╈綮膘━饱牓╈綮鄭竲h? 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